農業(yè)固體廢棄物催化氣化制取富氫燃氣基礎研究.pdf

1、東南大學碩士學位論文農業(yè)固體廢棄物催化氣化制取富氫燃氣基礎研究姓名：劉文杰申請學位級別：碩士專業(yè)：環(huán)境工程指導教師：仲兆平20070101AbstmctABSTRACTUsingAspenPlussoftwareofthethesmallestGibbsFreeEnergyPrinciples，balancingcalculatetheprocessoftheagriculturalsolidwastegasificationTheen

2、tirebalancecalculationisbasedonthemassbalance，thechemicalbalanceandtheenergybalance1specttheinfluencefactorsofthegasificationofsolidwaste，suchasreactingtemperature，Thesteamrationsolidwaste(s／w)andthepressureandsoon，andin

3、itialidentifythereactingconditions：800。C，S／W10IMpaUndertheinitialgasificaitionconditionsdeterminedbybalancecalculation，usethesolidwastegasificationexperimentispectthepropertiesofthecatalystpreparedbyimpregnationmethodBar

4、leystrawsarcchosenasthetypicalagriculturalsolidwastetoevaluatethepropertiesofthecatalystandweinvestigatetheeffectsofcatalystperformancecausingbypreparationparameterssuchas：pre仃eatmentofcatalystvectorofolivienandactiveA12

5、03，ImpregnationmethodtheloadingofactivecomponentNi，pHvalueofimpregnantsolutionandsoonTherelustsshowthatforthecatalystvectorofolivine，theNicontentof9％hasthebestcatalyticactivityinthelowtemperatureandtheNicontentof6％ismore

6、appropriateinthehightemperature；forthecatalystvectorofactiveA1203theNicontentof6％hasthebestcatalyticactivitywhereasinlowtemperatureorinhightemperatureAsthecatalystvectorsofolivineandactiveA1203，theloadingofactivecomponen

7、tNiarcnotcheap，soonthecheapbrickcatalystvectorbypretreatedhydrochloricacidandnitricacidimpregnatingandloading10％cheaperactivecomponentsZnandCathisimpregnationcatalyst’spropertiesachieveorexceedloadingNiimpregnationolivin