零維、一維及多維3d和4d配合物的設計與功能性研究.pdf

1、南開大學博士學位論文零維、一維及多維3d和4d配合物的設計與功能性研究姓名：王文珍申請學位級別：博士專業(yè)：無機化學指導教師：王耕霖2001.5.1南開大學博士學位畢業(yè)論文摘要AbstractAtotaloftwenty—fivenewcomplexeshavebeendesignedandsynthesized，amongthemthirteenhavebeenstructurallycharacterizedbyXraycrystal

2、lographicmethodsStudiesbasedOnelementalanalyses，皿Esgelectronicspectra，cyclicvoltammetryandvariabletemperaturemagneticsusceptibilitymeasurementshaverevealedsomeinterestingresultsTheelectronicspectraandESRspectraformononuc

3、learCu(n)complexes，andmagneticinteractionbehaviorsofsomeselectedpolynuclearcomplexeshavebeentheoreticallyanalyzedrelatedtotheirmolecularandelectronicstructuresThecouplingmechanismofaferromagneticallyinteractedCu(II)compl

4、exwithstrictlyorthogonalmagneticorbitalhasbeeninterpretedApairofhigh—spinCo(11)complexeswithlaydrogenbonded，three—dimensionalstructureshavebeenobtained，andthespectraandmagneticpropertieshavebeenstudiedOnethree—dimensiona

5、lsupramolecularnetworkandtwonoveloxamylcomplexesoneisahollowtetranuclearmoleculeandanotheriSaninfinitechainstructurewithnewcoordinationmodehavebeenobtalnedviaselfassemblemethodThecrucialroleoforganiccationonthecrystalliz

6、ingprocesshasbeendiscussedAseriesofRu(111)，Ru(II)，andmixedvalenceRu(win)complexeshavebeensynthesizedBesidesthemagneticstudiesofbinuclearRu(1II)complex，spectrainvolvingIVCTofmixed—valenceRu(II／III)complexesalsohavebeenana