偶氮苯類表面活性劑的合成和基本性質(zhì).pdf

1、東北師范大學(xué)碩士學(xué)位論文偶氮苯類表面活性劑的合成和基本性質(zhì)姓名：李香輝申請(qǐng)學(xué)位級(jí)別：碩士專業(yè)：分析化學(xué)指導(dǎo)教師：王廣20080501Abstract1Thesurfactantcanbellsedinsimulatingmemb姍estrI1cture，technologyofsy“hesiz抽曙U3membraIle，andasmediaorcon仃ollingthereleasefordye，quantumdot鋤ddrLlgctc

2、，aSwellasrelatiVefieldsnerefore，itisi“l(fā)ponaIlttodesignands”mesizesulfactam、7lritllpanicularstnlctmeaIm劬ctionsThis甜icledesignsandsynthesizet、vokilldsofnew吼】rfactantThefirstoneisahrldofnewsurfactantAzo—AOT，whichdealsw砒lnle

3、admtionofa面benzeneWhichreactS、Ⅳhenmeetsligmtosurf她tam2一(2ethylhexyI)sulfosuccinate(AoT)，mu5creatingakindofsurfactam(azo—AOT)cont撕ninglightactiVeazobenzenegmupTheotheroneisasm‘factantofblockcop01”nI。r砌chcon：tains1ightacti

4、、，e觚dacidactiVepyri曲1eazobenzenegroupSynthesizing鋤sslIr缸tant廿啪u曲AtomTransfcrIⅫicalP01)恤erization(ArRP)。’nlestructlIreandpropeniesof也e押，onews刪f_actamwascha“Ic州zedbyV赫ousmea工lssuchasnudearmagneticreson袖ce(1HN躲)、UVvisandIn丘

5、aredspe曲丑Thisdissenationconcemstheadditionofazob眥enegmup趾dpyridineazobenzenegrouptotllesurfactantm01ecule，wKchm出【estl】【empossibletoreVersiblycon虹olthefonningandbrca“ngdownofⅡ1ecapsuleu11derlightirradiationoracidT11isisbe

6、causeofazobenzenegroupcanhavereversiblecistransisomerizationunderthcirradiationofUVVisibleli曲tandtheni仃ogenatomofpyridinecaninco砷oratetoacid，血rtherthesee舵ctswillcausethebrea：kingdownaIldncwf0朋rliI培ofthec印suleTherefore，me

7、processofformingtllecapsulein也esolV咖canbecontrolledbymaIlymethods，whichmakethesurf&劬t晰11be謝delyuscd，2Much抽terestfocusesontheexplorationoff醣roelectricliquidcrysta1bccauSeithasspecialfeaturesuchasfaStrespoIlsecomp撕ngwimliq

8、umc叫staIChiralmoleculars帆lctu腭c鋤endowthem舢嘶als晰thpropertyofferroelectricliquidcrystal，sowein：troducetllect曲lsulfbone掣Dupimotheliquidcrystalmoleculet0fabricatethefeⅡoeIec仃icliquidcr)，stalm酏erialThemoleculars仃Ilcturewascon

9、nrmedbymassspectrometry(MS)，NuclearMa印甜cResonance(HNMR)andUVspectra(LⅣspec仃ophotometer)ItisexpectcdtohaVe也eprope啊offerroel。clricliquidcrys詛laIldpotentialapplicati曲Ke)rwords：Sl】而mant；AoT；丸ⅪbeI瑚nc；P蜘dineAzobenzene；Pl曲isome