四氮雜環(huán)蕃CP-,44-的修飾、分子識別和含氮雜環(huán)二茂鐵磺酰胺的合成研究.pdf

1、西北大學(xué)碩士學(xué)位論文四氮雜環(huán)蕃CP的修飾、分子識別和含氮雜環(huán)二茂鐵磺酰胺的合成研究姓名：朱愛林申請學(xué)位級別：碩士專業(yè)：有機(jī)化學(xué)指導(dǎo)教師：楊秉勤20040530西北大學(xué)碩上學(xué)位論文AbstractTe娜yclophaneisakindofimportantcorntⅪundincyclophane，andakindofcompoundwhichcanactashostinhostguestchemistryAsartificialenzy

2、mes，usinghydrophobiccavities，theyCallcapturedifferentorganicmoleculetoformthehostguestsystem，basedthedifferenceoftheringsite，sizeandinteractionAzaparacyclophaneplayasignificantroleinthesimulationofenzymefunctioninsomeorg

3、anicreactionsystemtomimicthebindingofsubstratesandcatalyzethereaction，consequentlycontrolthereactionspeciallyandincreasethereactionvelocityBychangingtheringsiteandsizeormodifyingthecyclophanewiththeactiveunitwecandesignt

4、henovelactivecenterwithcoordinatedinclusionandmultirecognitiontogetthespecialhost，whichwouldformthesupramolecularsystemwiththeguestandactualizethemolecularrecognitionandthesimulationofenzymefunctionInthePart1，thetwobioac

5、tiveunitswereintroducedinto1620，25tetraazN6161]paracyelophane(CP44)togetthefourtetraszaparacyclophanederivativeswiththebioactiveunitsThemolecularrecognitionbetweentheC％andthenitrogenheterocycficcompoundswereresearchedthr

6、oughtheMSandIllTheapplicationofferroceneandthederivativeshavebeenattachedtheimportanceinmanydomains，especiallyinthefieldofmedicine，biochemistryfuel，catalyzerInthePart2，ninenewnitrogenheterocyclicferrocenesulfonylamineswe

7、resynthesizedfromferrocenesulfonylchlorideandthenilrogenheterocycles(Indole，Morpholine，Imidazole，12，3一BenzotriazoleandBenzimidazolederivatives)，whichwereconfirmedby1HNMRIRandElementalanalysisUnderthemicrowaveirradiation，

8、therearemanybenefitsfororganicreaction，suchasshortreactiontime，highyield，lesswasteresidue，easypurification，lesspollution，whichhavewonwideattentionTheMicrowaveInducedOrganicReactionEnhancementChemistryisnowfoundwideapplic