磺酸銀與含氮配體配位聚合物的合成、結(jié)構(gòu)及表征.pdf

1、學(xué)校代碼：10200分類(lèi)號(hào)：06l@東牡知爺葒大孽碩士學(xué)位論文研究生學(xué)號(hào)密級(jí)88970IWUHUA2006無(wú)磺酸鍛與含氮配體配位聚合物的合成、結(jié)構(gòu)及表征Syntheses，structu心sandCharacterizesofSilver(I)SulfonateCoordinationPolymersContainingNitrogenLigands作者：吳華指導(dǎo)教師學(xué)科專(zhuān)業(yè)：研究方向：學(xué)位類(lèi)型：馬建方教授無(wú)機(jī)化學(xué)配位化學(xué)高校教師東北師

2、范大學(xué)學(xué)位評(píng)定委員會(huì)2006年5月AbstractThepresentstudyrepresentsthesystematicexaminationoftheef琵ctsonthesilVer(I)sulfonateincorporatingneutralligalldsEightsilver(I)sulfonatecoordinationsolidsarer印onedThes01idstatestnlcturesofsilver(I)

3、disulfonatesincorporatedfourdi位rentskindsofneutral1igands，whichare(3一iso=3methylisoquinollne，amonodentatelgand；bipy=4，4’一bipyridine，arigiddive唱entbidentate1igand；b訂m=1，1’一(1，4butanediyl)bis(imidazoIe)，aflexibilitydiverge

4、ntbidentateligand；hmt=hex鋤etllylenetetramine，apotentialte仃adentatelig柚d)(Scheme1)Eightnovelsilver(I)sulfonateshavebeensyntllesizcdsuccessmllyHerein，wedescribethedetailsofthepreparationandcharacterizationofmeeightnovelsil

5、ve“I)polymers：[A92L(3一iso)2】[AgL3】‘5H20(1)，【A92(bipy)2(H20)】【AgL(bipy)】7H20(2)，【A甄biim)】【A92(biim)2L】(3)，【A踟L(tm岣2’3H20】’H20(4)，Ag【K5L2】‘2H20(5)A1lcryStalstmctureshaVebeendete肌inedbysingle—crystalXraydi冊(cè)actionandthecompo

6、uIldsarealsocharacterizedbyIRaIldelementala11alysesCompound1possessdiscretestructure，whilecompounds25showpolymericstnJctures誦tlldiffbrentdimensionalities，respectivelyMoreoVer，thecompoundsl醐d2fomed3Dsupr鋤olecuIarsnllc“l(fā)re