手性酒石酸稀土配合物的合成、結(jié)構(gòu)、熒光及催化性能研究.pdf

1、黑龍江大學(xué)碩士學(xué)位論文手性酒石酸稀土配合物的合成、結(jié)構(gòu)、熒光及催化性能研究姓名：邢景春申請學(xué)位級別：碩士專業(yè)：有機化學(xué)指導(dǎo)教師：閆鵬飛20080511黑龍江大學(xué)碩士學(xué)位論文AbstractAseriesofchimlorracemictartratel觚tll粕ide(III)compIexeS，haVebe饑sp【mesizedtllrou曲hydrome肌alsyllmesisintllisp印erandcharaCterizedb

2、yeleme砌鋤alySis，IIl危玳dspectm(IR)，ThemaJ粵aVime仃ic鋤dLuminescencespectra耵leya陀diVidedintotllI優(yōu)kindSaccordingt0di任erentraree卸脅s，namely，Ⅱ皿(DL／D一㈣3(H20)3】。15H20【Ln=La(1)，Nd(2)，Sm(3)，Eu(4)】，【Ln2(Dtan)3(H20)2】‘3H20【Ln2Tb(5)，Dy(6)

3、，Er(7)】，【Lu2(D—ta：吶4(H20)5】【Ln=Lu(8)】，tan=【C4H406】一ComplexeSl、5、8havebeensnuctu蹦lycharacterizedbysiIl酉e吒DrstalX—rayc巧srallog嘲蚰caIlalySisTheStructuredetemination湖慣lstllatcompleX懿1粕d5are3D鵬t、)vo噸c0InpleXe8is2一Dlayer，鋤dthes

4、缸1ItureforcompleXe1previouSlyw弱mmponedhlme∞complexes，tln撕c∞idlig鋤dexllibit弱仃identatc，tet豫d朗tate，pentadentate雒dhexadentatec00rdinationmodes，and“iscXcellentbuildingblocl(sformeconS仃uctionofthe鼬pr鋤olecularSystem0v西ngt0tllec

5、oordimmonsitesofhydroxyl鋤dcad’oxylate罌。oupsLl刪面eScentspectra0fcomplexleXhibitSligandlⅦm艙ScenCeCompleXes2~5礎(chǔ)bitmetaLlc即teredlumineScenCeAs)，Imnetrictransferhydrogenationof∞etophenonebyuSiIlgcompleX3wasconduCted觚ditw弱found