離子液體聚合物電解質(zhì)的制備和性能研究.pdf

1、分類號(hào)泫尚六。罨碩士學(xué)位論文題目：查王速笠盈金塑電鰹亟笪劍鱉塑壁篚盟窒英文并列題目：S地盤笪盟!絲墮堡塹亟P堂!煎i曼墨密級(jí)研究生：型坌籩專業(yè)：廛旦絲堂研究方向：生絲堂皇能退壁查導(dǎo)師：張海朗副教授孥位授予日期：!QQ生旦!i日答辯委員會(huì)主席：宋啟軍教授江南大學(xué)地址：無錫市青山灣二00六年打月●摘要Abstract10n—Hqujd刪珊erelectmlytes(J廿E)haves啪eSpedaladVantages，whjchwerep

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3、nacidcaljonexchangeresjnand4一methylbenzenesulfonicacid，werestIldiedTcchnicsconditionsofesterjficationreactjonwerc叩timizedtllfoughonllogonalexperiments，s0theidealrcacti咖condilj徹swerethereadiontemperatufe85℃，tllem01armtio1

4、3：1(PEG／methacrylicacid)andcatalyst4％叭(thetotalweiglltofthePEGandmethacrylicacid)secondlyB卜PEGMMAweresynthesizedwithPEGMMAaIldPBr3throu業(yè)bmminationreactionAfIerthesimplef犯toTanalysisexperime玎ts，theOptimaloperationconditio

5、nswercdecided：them01arrati02：1(PEGMMA／PBr3)，reactingsubStaIlcec咖centration05m01L1，dmppjngliquidtemperature45℃andreactiontemperature70℃1’heirconductiVitieswerc1，7410。jScm‘1and617X104Scm～，fespectiveivat30℃whichweredependen

6、tofthe打VjscositjesUsingB卜PEGMMAandpyridinetosynthesizepyridiniumsalt，theirViscositiesandconductiVitieswefestudiedT1IeVjscositieswerehigherthanthatofBrPEGMMA，buttheiOnconductivitjeswerenotconsistentwiththeviscositiesAt30℃

7、，theirionconductiVjtieswercrespectiVely251Scm～and105Scm～FourIu慢，P1皿O4，Br)、P2(EO9，Br)、P3(Eo4，BF4一)，andP4(E09，BF4_)，weremanufacturedthrou曲twostepsindudingpolymerjzationreactionsandcatjonsexchan百ngreactionsTheirionconductiv

8、itiesandDscwereinvestigatedcomparingdjfferent(Eo)unAnumbefswithcalions，thedi骶renceaboutjonconductiVjtieswereanalyzedAt30℃，thejonconductiVitiesofP1姆dP3wefe274lo_6S鋤。1(1售40℃)and343x108Scm。1(T舀一39℃)；P2andP4，30410。6scm‘1(Tg，

9、29℃)and607108scm一1(Tg，27℃)，fespectivelyneywefeselfconducliVebodjesAndtheirjonconductiVitjesweleindependentoftheirViscositiesTheresultwasthatthemostimpoItantfactoLwhichinnuencedthepolymersconductivities，wasthecatjon立，that