硫代酸酯類(lèi)配合物的合成、結(jié)與性質(zhì)研究.pdf

1、安徽大學(xué)碩士學(xué)位論文硫代酸酯類(lèi)配合物的合成、結(jié)與性質(zhì)研究姓名：湯英文申請(qǐng)學(xué)位級(jí)別：碩士專(zhuān)業(yè)：無(wú)機(jī)化學(xué)指導(dǎo)教師：田玉鵬謝復(fù)新2001.5.1^AbstractTheaimofthisthesisisexplorethepropertiesandsynthesisofthirdordernonlinearopticalmaterialsforhydrazinecarbodithioicacidphenymethyl(methyllester

2、andthiosemicarbazidehavingcarbazoland4【N，N—Bispropylamino】phenyl0nthebasisofinvestigationandstudyofalotofliterature，wefindthattherearemanycomplexesexhibittingobviousNonlinearopticalresponseButthecomplexeswhichwehavesynth

3、esizedrarelybestudied1Summary2WeuseHydrazinecarboditoicacidphenymethyl(methyl)ester，thiosemicarbazideandN‘ethyl3formylcarbazole，4IN，NBispropylamino]benzaldehydeasmaterialstosynthesizetheligandsHLl，HL2，HL3，HL4，HL5，HL6，whi

4、charecharacterizedbyIR，UV，Elementalanalysis，MS，TGACrystalsofHL2，HL3，HL4，H0，HL6areObtained，Ho，HL6havebeendetermined3Ni(L1)z，Cu(L1)：，ed(L1)：，Ni(L2)：，Cu(L2)2，Pd(Lb：，Ni(Ls)2，Ni(L4)2，Cu(L4)：，Pd(L4)2，Cd(L4)2，Zn(L4)2，Ni(Ls)2，Ni

5、(L6)2，Cu(L6)2(M：L=1：2)areprepared，thesecomplexesarecharacterizedbyIR，Uv’ElementalanalysisandTG，electricalconductanceandX。raycrystaldeterminationThecrystalstructureofNi(L2)2，Ni(L4)2，Ni(Ls)2havebeendetermined4wecarryoutthe

6、reseachofphot01uminescenceoftheallcomplexesandligandinsolid，Theresultshowsthatthea11ligandsandCd(L32，Zn(L4)!havethephenomcnonofphotoluminescence，buttheothercomplexesdon’thaveThethird—ordernonlinearopticalpropertiesoflL2，