2053.質(zhì)子化酞菁銥配合物的光譜調(diào)控研究

1、學(xué)校代碼：10270分類號：O61學(xué)號：142200687碩士學(xué)位論文質(zhì)子化酞菁銥配合物的光譜調(diào)控研究學(xué)院：生命與環(huán)境科學(xué)學(xué)院專業(yè)：無機(jī)化學(xué)研究方向：光功能材料研究生姓名：鄧晶晶指導(dǎo)教師：楊紅教授完成日期：2017年3月上海師范大學(xué)碩士學(xué)位論文AbstractIIIAbstractWiththedevelopmentofphotoelectrictechnologyphthalocyaninehasbeenwidelyappliedin

2、thefieldofLBfilmopticalstagemediumenergyconversionmaterialssemiconductsetc.Inthispaperwesynthesizedaprotonatedphthalocyanineiridiumcomplex(IrPcHCl2)focusingonaseriesoffactstocontroltheabsptionspectrumitsmechanismffurther

3、study.Themaincontentsincludethefollowingthreeaspects.1.SpectralRegulationofIrPcHCl2bysolventconcentrationTheiridiumcomplexeswithphthalocyanineastheligweredesignedsynthesized.ThestructuresofIrPcHCl2wereacterizedby1HNMRhig

4、hresolutionmassspectrometry.TheabsptionspectrainCH2Cl2CHCl3THFDMSODMFCH3CNweretested.TheresultsshowthatthesymmetryoftheprotonatedphthalocyanineringchangesmakingtheQbofIrPcHCl2split.IrPcHCl2showeddeprotonationinDMSODMFCH3

5、CN.TheeffectsofconcentrationonIrPcHCl2spectrawerestudied.TheconcentrationofIrPcHCl2didnotoccurintheexperimentalconcentrationrange.2.SpectralregulationofIrPcHCl2byacidTheeffectsofCF3SO3HCF3CO2HontheabsptionspectraofIrPcHC

6、l2werestudiedinTHFCH2Cl2benzonitrile.TheresultsshowthatthestrengthoftheacidthepolarityofthesolventaffecttheprotonationofIrPcHCl2whichcancausethechangeoftheabsptionspectrum.3.SpectralregulationofIrPcHCl2bysilversaltThewki

7、nthissectionrevolvesaroundthespectralcontrolofIrPcHCl2infoursolvents(AgBF4CF3SO3AgCH3COOAgCF3COOAg)intwosolvents.Duetotheanionofthealkalinecodinationcapacityofthedifferencescausedbychangesinthespectrum.Howeverothermetali