21810.手性聯(lián)苯酚類(lèi)inmof的設(shè)計(jì)、組裝與性能研究

1、學(xué)校代碼：10270學(xué)號(hào)：122200790碩士學(xué)位論文論文題目：手性聯(lián)苯酚類(lèi)InMOF的設(shè)計(jì)、組裝與性能研究學(xué)院：生命與環(huán)境科學(xué)學(xué)院專(zhuān)業(yè)：有機(jī)化學(xué)研究方向：金屬有機(jī)研究生姓名：林小超指導(dǎo)教師：劉國(guó)華教授崔勇教授完成日期：2015年3月11日Abstract上海師范大學(xué)碩士學(xué)位論文IIAbstractThefieldofChiralMetalganicFramewks(CMOFs)representsaburgeoningareawit

2、hversatileapplicationsinvariousaspectssuchasheterogeneouscatalysischiralrecognitionseparationenantioivesensetal.InthisthesisanaxiallyC2symmetricBiphenylscaffoldwithcarboxylfunctionalizedganiclinkerwassynthesizedfurtherut

3、ilizedtobuildchiralpouscrystallinematerialwithIn3.ThismaterialiswellacterizedbyXRDEAIRTGAetc.Theywereverystableappliedtochiralrecognitionseparationchiralfluescencechiralinducedcrystallization.Thethesisincludesfourchapter

4、sasfollows:InthefirstchaptertheresearchprocessofCMOFsisbrieflyintroducedincludingtheirsyntheticapproachesapplicationsinheterogeneouscatalysischiralrecognitionseparationaswellaschiralsensthenthesignificanceoverviewoftheth

5、esiswerepresented.InthesecondchapteranaxiallyC2symmetric11′biphenolligH4Lwassynthesizedvianinestepsusedtobuildahomochiralnanopous(R)InMOFwithInCl3throughselfassembly.ThismaterialiswellacterizedbyTGACDPXRDBETetc.Inthethir

6、dchapterthematerial(R)InMOFwasdemonstratedtobeanexcellentsolidstatehosttoenantioivelyadsbseparatearomaticsulfoxidesderivatives(upto97.7%ee).Thehostmaterialcanbereadilyrecycledreusedwithoutanyapparentlossofenantioivity.Th

7、ematerial(R)InMOFwasdemonstratedtobeachiralsenswithanumberofchiralsugars(Ksv=5.820.18)(R)InMOFwasusedtoinducesaturatedalaninetoproducechiralcrystalsasachiralinducedmedium(upto93%ee).Inthefourthchapterabriefconclusionoutl