[60]富勒烯與共軛二烯體的Diels-Alder環(huán)加成反應(yīng)的研究.pdf

1、華南師范大學(xué)碩士學(xué)位論文[60]富勒烯與共軛二烯體的DielsAlder環(huán)加成反應(yīng)的研究姓名：文麗君申請(qǐng)學(xué)位級(jí)別：碩士專業(yè)：有機(jī)化學(xué)指導(dǎo)教師：楊定喬曾和平2003.5.1ABSTRACTBulkminsterfullerene(C印)hasbeenoneofthemostbrilliantstarinthescientificfieldswithitsfamilysinceitwasfoundin1985％hasthreedimensi

2、onalconjugatedstructnreperfectsymmetryandsmallrecombinationenergywhichl／lakeitanditsderivativesbefullofuniquepropertiesandpotentialapplicationincatalystsuperconduction，magnifydevices，bioactiveandsoon；C60isagoodelectronac

3、ceptorcanmakeD—Amolecularwhichisappliedtophotovoltaicdevicesdesigning；theuniquesphericalstructuremakeC砷beofsomeproperdesofelectrondeficientpolyolefin，amongthemanyderivativesmethodsavailable，oneofthemostefficientorganicfu

4、nctionalmethodisDiels—AlderreactionInthispaper23dibromomethyl5，6一pyrazinedicarbonitrilewaspreparedfrom23dimethybS6一pyrazinedicarbonitrilethroughradicalbrominationwhichisdi伍：rentfromthereferencesthestructurewasidentifiedb

5、ymP，UVMS，and1HNMRThe7chloro[1，2，34】一tewahydrophenazine【23】一fullereneC酗hasbeenfirstlypreparedbytheDiels—AlderreactionofC60with6cMoro2，3bis(bromomethyl)‘quinoxaline，whichwasobtainedbythecondensationreactionof14dibromo23一bu

6、tancdionewith4chloro一1，2phenylenediamineThestnlctureofthecompoundwasidentifiedbyWIR，MS，1HNMRandbCNMRTheopticspropertytheelectronselebrationandmolecularstructureofthecompoundalsoareresearchedinthispaperKeywordsFuUerene(C6